[AMMRL] Chlorine NMR for trace compounds in bulk Cl- electrolyte?

From: Wendy Breyer <web216_at_lehigh.edu>
Date: Tue, 09 Apr 2024 12:49:22 -0700

Hi all,

I'm looking for some advice on the feasibility of some proposed experiments. 
A user here would like to do Cl-NMR on aqueous electrolyte solutions. 
Specifically, he would like to check for small amounts of OCl- and dissolved Cl2
in the presence of 3M MgCl2.  After searching the literature, I have been
unable to locate any publications that include similar experiments so I suspect
that his proposed experiments are not feasible... but my knowledge of NMR is
superficial at best.   I'd be very interested in hearing from those
with more experience whether these experiments are possible.  (For context,
we have a 400 MHz Avance III HD with a room temperature, broadband probe.)

Thanks for any input!

Wendy


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Received on Tue Apr 09 2024 - 16:47:25 MST

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