Re: phosphorus chemical shifts

From: Edward T. Chainani <etch_at_ginto.chem.admu.edu.ph>
Date: Thu, 1 Apr 2004 07:54:03 +0800 (PHT)

Hi,

You can try:
1) Multinuclear NMR. Edited by Joan Mason. Plenum Press. 1987
2) Physiological NMR Spectroscopy: From Isolated Cells to Man. Annals of
the New York Academy of Sciences, Vol. 508, 1987.

Hope this helps,

Edward

On Wed, 31 Mar 2004, Robert Wiseman wrote:

>
> AMMRLers-
>
> We have been working with a small cell bioreactor doing phosphorus NMR to
> detect chemical potential changes arising from glucose challenges. We
> have done some extracts and found many resonances in the sugar phosphate
> regions that do not correspond with what we expected. These are likely
> glycolytic intermediates I suspect. I have been looking for a good
> reference (book or manuscript) that describes the chemical shift positions
> of biologically active phosphorus compounds at pH ranges from 6.9-7.1. I
> recall a book in the mid to late 80's that had a chapter dedicated to this
> that included every biologically active phosphate compound, its chemical
> shift and the pKa if it was an ionizable compound. I do not recall the
> reference and have been unable to locate the book, does anyone recall this
> chapter?
>
> Any recommendation for a decent paper would also be quite helpful. I have
> found references for phosphorus compounds in general, even some web
> sources, but specific glycolytic intermediates were not listed.
> Thanks
>
>
>
> Robert W. Wiseman, Ph.D.
> Associate Professor of Physiology and Radiology
>
> Shipping and Mailing Address:
> Michigan State University
> Department of Physiology
> 2201 Biomedical and Physical Sciences Building
> East Lansing, MI 48824
>
> email: rwiseman_at_msu.edu
> alternative email (for files larger than 500 KByte): rww_at_rad.msu.edu
>
> office 3198 BPS Building
> 517-355-6475 (x-1151)
> laboratory 3110 BPS Building
> 517-355-6475 (x-1342)
>
>

-- 
Edward T. Chainani
Chemistry Department &
National Chemistry Instrumentation Center (NCIC)
Ateneo de Manila University         
Loyola Heights, Quezon City         
Philippines
phone:  (632) 426-6001 loc. 5628
FAX: (632) 426-1323
e-mail: etch_at_chem.admu.edu.ph
Received on Wed Mar 31 2004 - 19:49:18 MST

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