Re: [AMMRL] Silicone-HMBC help

From: Akien, Geoffrey via groups.io <g.akien=lancaster.ac.uk_at_groups.io>
Date: Sat, 18 Apr 2026 14:59:26 +0000

Hi Ted,

If you adapted the HMBC parameter set from another nucleus, the usual
candidate is 1 SR being set to some unreasonably large value. Set it to zero
and wpar the parameter set so its correct for the next time you use it.

Thanks

Geoff
________________________________
> From: main_at_ammrl.groups.io on behalf of Wiessner, Tedd via groups.io
> Sent: 17 April 2026 18:40
< To: main_at_ammrl.groups.io <main_at_ammrl.groups.io>
> Subject: [External] [AMMRL] Silicone-HMBC help


Hi All,

We are trying to implement a silicon-HMBC experiment and are having trouble
getting the Si-axis to be in the range we want.

The sweep width we were going for was 200 ppm centered at -40 ppm, but the
spectra we keep getting are labeled as ranging from 960,777 to around 960,384 ppm
(SW~400 ppm). Does anyone have any ideas why this is happening and how to fix it?
I feel like I am missing something simple but am at a loss.

For reference, the spectrum below is of tetraethoxy silane (~-81.8 ppm).

Thanks!

Best,

Tedd

Tedd C. Wiessner, PhD
Senior Scientist I, Pathways Manager, Analytical Lab | H.B. Fuller Company
1200 Willow Lake Blvd | Vadnais Heights | MN | 55110 | USA



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Received on Sat Apr 18 2026 - 08:01:42 MST

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